In a large bowl, mix flour, granulated sugar, brown sugar, baking powder, baking soda, espresso powder, and salt together.
Make a well in the center of the dry ingredients (push the dry ingredients up around the sides so there’s a hole or ‘well’ in the center—this helps disperse the wet ingredients better).
Pour in the buttermilk, oil, brewed coffee, and eggs.
Gently mix the batter until the wet ingredients are just mixed in (the batter will still be very dry at this point).
Add in the sour cream and vanilla extract, and mix until all of the ingredients are just combined.
Lastly, add in the mini chocolate chips and mix until combined.
Fill the muffin tins about 2/3 of the way full with the batter. The batter makes about 12-14 muffins.